Dangerous goods are categorised into 9 major groups, each depicting a significant hazard associated with the use or transport of the substances in that classification. Some classifications have sub-groups to provide a more accurate description of the hazard and composition of the material.

Explosive substances and articles 1 Explosive substances and articles

Explosive substances that are capable of producing causing damage to the surroundings by explosion, and pyrotechnic substances that are designed to produce a heat/light/sound/gas/smoke effect.

Flammable gas 2.1 Flammable gases
Non-flammable, non-toxic gases 2.2 Non-flammable, non-toxic gases
Toxic gases 2.3 Toxic gases
Flammable liquids 3 Flammable liquids

Flammable substances which are liquids, and molten solid substances

Flammable solids, self-reactive substances, polymerizing substances and solid desensitized explosives 4.1 Flammable solids, self-reactive substances, polymerizing substances and solid desensitized explosives
Substances liable to spontaneous combustion 4.2 Substances liable to spontaneous combustion

Pyrophoric and self-heating substances

Substances which, in contact with water, emit flammable gases 4.3 Substances which, in contact with water, emit flammable gases

Substances that react with water to emit flammable gases, which are liable to form explosive mixtures

Oxidizing substances 5.1 Oxidizing substances

Substances which my contribute to a combustion process by providing oxygen

Organic peroxides 5.2 Organic peroxides
Toxic substances 6.1 Toxic substances

Substances that in relatively small quantities can cause death or damage to human health

Infectious substances 6.2 Infectious substances
Radioactive material 7 Radioactive material
Corrosive substances 8 Corrosive substances

Substances which attach tissue, or which in the event of leakage are capable of damaging or destroying other goods

Miscellaneous dangerous substances and articles 9 Miscellaneous dangerous substances and articles

Substances which, during carriage, present a danger not covered by any other heading

ADR European Agreement Concerning the International Carriage of Dangerous Goods by Road, ECE/TRANS/257 (Vol. 1), Economic Commission for Europe Inland Transport Committee, UNECE 2017